Publication date: 30 January 2026
Source: Journal of Metastable and Nanocrystalline Materials Vol. 43
Author(s): Zahraa Ali Hassan
The Rhodamine 6G fluorescent dye, It was dissolved at a concentration in ethanol of 6*10-6 M, was investigated an active laser medium in this work, and its optical and spectral properties were investigated. The fluorescent Rhodamine 6G dye, which was dissolved in ethanol at a concentration 6*10-6 M, was investigated an active laser medium in this work, and its optical and spectral properties were investigated. The chemical reduction process was also used to create gold nanoparticles at concentration of 0.01 M. Three concentrations of gold nanoparticles (2.5, 5, and 7.5%) w/v were added to the Rhodamine 6G dye solution in order to examine how they affected the dye's optical and spectral characteristics. Optical and spectral properties Rhodamine 6G dye sample were analyzed both before to following the addition of gold nanoparticles. After adding gold nanoparticle the dye, the results indicated a shift toward lower wavelengths (red shift) and an increase in optical parameters, with the exception of transmittance. Fluorescence intensity, radiative lifetime, quantum yield, stoke shift, and fluoresce cent lifetime were among the spectrum characteristics. The relative fluorescence intensity dropped after the nanoparticles were applied.
[1] F.P. Schafer,"DyeaLaser",aSpringeraVerlagBerlin,aHeidelbergANewYork, (1977).
[2] S. Terdale and A. Tantray, "Spectroscopic study of the dimerization of rhodamine 6G in water and different organic solvents," J.Mol. Liq., vol. 225, p.662–671, 2017.
[3] B. Hederson, and I. M. Imbusch, "Optical Spectroscopy of Inorganic Solids ", Clarendon press, Oxford, U.K, (1989).
[4] Photoluminescence of rhodamine 6G in plasmonic field of Au nanoparticles: Temperature effects Oleg A. Yeshchenko n, Illya S. Bondarchuk, Viktor V. Kozachenko, Mykhaylo Yu. Losytskyy, Journal of Luminescence 158 (2015) 294–300.
[5] O. Svelte ,principles of laser, plenum press, New York, 1989. Linear and Nonlinear optical properties of Rhodamine 6G H.H. Obeed1, Khawla J. Tahir2*, Noor J. Ridha2, Firas K. Mohamad Alosfur3,4 and Rajaa Madlol2, IOP Conf. Series: Materials Science and Engineering 928 (2020) 072024.
[6] Shahid Ali Khan, Sher Bahadar Khan, Latif Ullah Khan, Aliya Farooq, Kalsoom Akhtar, and Abdullah M. Asiri, Fourier Transform Infrared Spectroscopy: Fundamentals and Application in Functional Groups and Nanomaterials Characterization, Handbook of Materials Characterization, September 2018.
[7] Key aspects of surface plasmon resonance spectroscopy for analytical chemistry applications, Lorean Madriz,1,2 Ronald Vargas3, Journal of Analytical & Pharmaceutical Research, Volume 7 Issue 4 – 2018.
[8] Y.H. Khadim, M.M. Mehdy Al- Sultani, Study of the spectral characteristics for the Styryl 9M laser dye, International Journal of ChemTech Research, Vol.10 No.9, pp.646-653. 2017.
[9] Dr. Adnan F. Hassan, Alaa Meahdy Mohamed, Study the Optical Characteristics of the extraction Pigments from Vinca flowers, Journal University of Kerbala, Vol. 14 No.4 Scientific. 2016.
[10] Sara Jawad Shoja , Study of Spectroscopic and optical Properties for phenolphthalein dye as a laser active medium , College of Science for Women , University of Babylon ,(2016)
[11] Suhad Heyawi Mohsen, Luminescent concentrators based on two organic dyes to increase the solar cell efficiency, MSc. thesis, Kufa University, 2017.
[12] Mahshad G. and Davoud D., Effect of Ag-Nanoparticles Doped in Polyvinyl Alcohol on the Structural and Optical Properties of PVA Films, Hindawi Publishing Corporation Journal of Nanomaterials Volume, Article ID 897043, 2013.
[13] A.A. Muhmood, I.A. Zgair, M.A. Hussein, L.H. Mahdi, B. S.Jabbar, A.H. Omran, Preparation and optical characterizations of PVA: Ag Nano composite, Journal of Physics: Conference Series 1879 ,032083, IOP Publishing. 2021.
[14] Diemiruaye, J. M., Int. J. Thin Film Sci. Tec., 2 (2): pp.53-66. 2013.
[15] Joe Schwarcz PhD, 20 Mar 2017, What is Fluorescence?
[16] Influence of metal nanoparticles on fluorescence properties Vamsi K. Kandimalla, MASTER thesis, Michigan University, 2010.
[17] Shweta Verma, B. Tirumala Rao, A.K. Srivastava, H.S. Patel, studies on interdependent optical properties of Rhodamine 6G dye and gold nanoparticles at different dilutions of aqueous solutions, received 3 April 2014, Revised 3 June 2014, Accepted 17 June 2014, Available online 23 June 2014.